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The citizens,------,welcomed the new legislation 请问A项为什么不对?麻

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The citizens,------,welcomed the new legislation 请问A项为什么不对?麻烦加以解释下
A,most of who were workers
B,most of whom were workers
C,most of them were workers
of 是介词 ,在这个句子里后面就得是介宾这样的结构,而WHO是个主语,不能作为宾语用来的