英语翻译The salen ligand in 3 was prepared by hydrolyzing 7 and

来源：学生作业帮编辑：作业帮分类：英语作业时间：2024/10/04 22:19:58

英语翻译
The salen ligand in 3 was prepared by hydrolyzing 7 and reacting the mixed diamine with 3,5-di-tert-butylsalicylaldehyde.The crystal structure (Figure S2) and enantiopurity (>99% ee,Figure S1) of this ligand (L3) have been determined.The salen ligand (L3) was mixed with Co(II) nitrate in methanol and air oxidized
to obtain the Co(III) complex.

在3双的反应,合成了diaza-Cope重排反应在锅方案1).序贯增加了两个醛到4导致具有高效的可构造性的混合diimine(6),接着重排反应给7.这两个resonance-assisted氢键重新排列在7开车
反应完成.我们首先合成了一有限公司(3)复杂的7使用吡啶为基础.晶体结构公司(3)复杂的(图1)表明,喹集团坐标金属,从而迫使nitrophenyl集团占据轴向位置作为一整段使用.有趣的是,吡啶分子协调
对钴复杂和定位几乎平行于nitrophenyl组.这两组是关于3.26-3.90一个分开.
网上看到的.

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